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基于电子自旋极化磁耦合机制的原子层次可控自组装方案

成果领域: 新材料

推广方式: 技术许可,技术合作,其他

成果鉴定时间:

成果介绍

在理论上设计了一种基于电子自旋极化磁耦合的自组装方案途径。来自不同内嵌金属富勒烯型超原子基元上的自旋极化电子可以相互配对键合，以保证体系沿着一维方向延展。第一性原理的计算和分析表明，随着基元数目增加的链状排列体系总相互作用强度近于线性增长；体系的电子结构性质基本不受到基元数目的影响。以上结果证明了这种基于电子自旋极化的磁耦合自组装方法是可行的。并证明了在没有配体保护的情况下，由于超原子基元自身的核-壳结构和类原子的电子排列特点，使得基元在自组装过程中保持了电子结构的鲁棒性。

成果应用案例介绍

联系方式

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