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一种超临界水制备薄层多孔g-C3N4的方法

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成果归属企业: 深圳大学

成果鉴定时间:

成果介绍

本发明公开一种热电材料及其制备方法与复合热电薄膜。所述热电材料的结构通式如下所示：其中，R选自或本发明设计合成了一系列具有新型结构的蝶形有机共轭小分子热电材料，该材料以并五苯酮或奈环酮等具有较强场效应迁移率的平面共轭结构单元作为分子体系的结构中心(电子受体(Acceptor))，以噻吩环等芳香基团为蝶形分子的翅膀。通过嵌入不同种类的噻吩环芳香结构单元(电子给体(Donor))来构建具有不同二面角的并五苯酮或奈环酮结构。该系列分子具有共轭二维平面结构，通过对其骨架结构修饰可以调控HOMO与LUMO电子能级与能隙，同时可以优化分子π‑π堆积，从而获得较高的热电性能。

成果应用案例介绍

化学品>化合物>9, 10-二氢蒽-9-酮化合物; 材料制品>其它材料>热电材料; 材料制品>膜材>复合热电薄膜

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